The Removal of Cu2+ in Industrial Wastewater Using the Activated Carbon Derived from Mango (Mangifera indica) Leaves
Volume 3 - Issue 6, June 2019 Edition
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Author(s)
REJIE C. MAGNAYE
Keywords
Activated Carbon, Copper, Industrial Wastewater, Mangifera indica leaves
Abstract
The study focused on the test for the potentiality of Mango (Mangifera indica) leaves in producing adsorbent for the removal of Copper (Cu+2) in industrial wastewater. The percent removal of copper was analyzed through Atomic Absorption Spectrometry. The surface morphologies of adsorbent derived from mango leaves as well as of commercial activated carbon were determined through X-ray Diffraction Analysis. Experimental and linear and non-linear regression models were used in the determination of the efficacy of activated carbon from Mango leaves for the removal of copper from industrial wastewater. Two-way Analysis of Variance (ANOVA) and Independent t-test were used to test the validity of the hypothesis. The percent yield of mango leaves after activation was found to be 21.54%. It was also found that Mango leaves that had undergone chemical activation have higher metal adsorption compared to ordinary adsorbent. X-ray diffraction analysis revealed the mean particle size and particle size distribution while experimental method was used to obtain the bulk density and total surface area of the adsorbent from Mango leaves. The results of this study indicated that the uptake of copper metal from industrial wastewater was affected by factors such as dosage and contact time. The optimum condition for the reduction of copper metal was found to be at 0.75 grams’ dosage and 60 minutes’ contact time. At optimum condition, the percent removal of copper was 93.33 %. It was found that the effect of time does not depend on what level of dosage is present. Mathematical modelling was used to describe the capability of activated carbon to adsorb copper metal in industrial wastewater. Using Design of Experiment (DOE) software, the equation generated was Y= 0.1057 – 3.8295E-3*A + 2.5510E-5*B where Y was the percentage copper removal (%), A and B were actual variables for dosage and contact time, respectively. Based from the experimental and mathematical analysis, it had been shown that Mango leaves have potential in removing copper metal from industrial wastewater.
References
[1] Rashmi Verma and Pratima Dwivedi, 2013, “Heavy Metal water pollution – A Case Study, Biluspus, India
[2] S. Wang, H. Li, 2007, “Kinetic modeling and mechanism of dye adsorption on unburned carbon Dyes Pigmâ€., 72, pp. 308-314
[3] Okeola, O. F., Odebunmi, E. O. and Ameen, O. M. (2012). Comparison of Sorption capacity and surface area of Activated carbon prepared from Jatropha curcas fruit pericarp and seed coat. Bull. Chem. Soc. Ethiop, 26(2) 171-180.
[4] Awitdrus, et.al., 2010, “Microcrystallite Dimension and Total Active Surface Area of Carbon Electrode from Mixtures of Pre-Carbonized Oil Palm Empty Fruit Bunches and Green Petroleum Cokesâ€, Sains Malaysiana 39(1) pp. 83–86
[5] Sheen, O. P., 2011,’Utilization of Mango Leaves as Low-cost Adsorbent for the Removal of Copper Ions from Aqueous Solutions’, UniversitiTunku Abdul Rahman, India
[6] De Lara, M. L., Macalalad, H., and Marinay, J. A.,2006, ‘Treatment of Simulated Wastewater via Adsorption of Heavy Metals by Activated and Modified Peanut Shells’, Batangas State University, Batangas City
[7] Dina, D.J.D., Ntieche, A.R., Ndi, J.N., Ketcha J.M., 2012, “Adsorption of acetic acid onto activated carbons obtained from maize cobs by chemical activation with zinc chloride (ZnCl2)â€. Res J Chem Sci, 2(9), 42-49
[8] Sucharita, T. and Nanadini, N., 2009, Adsorption efficiency of carbon from treated sugarcane bagasse in removing chromium (vi) from aqueous solutions by optimization of adsorption parameters. Journal of Applied and Natural Science, 1(2): 155-158
[9] Villafria, M. C., and Yamit, C. R., 2011, ‘Utilization of Coconut Husks fibers in Producing Activated Carbon in the Reduction of Heavy Metalls in Simulated Wastewater’, Batangas State University, Batangas City
[10] Arroyo, I. M., Caponpon, E. H., and Limbo, D. A., 2006,’Utilization of acid-modified Corncobs in the Adsorption of Heavy Metals fom Simulated Wastewater’, Batangas State University, Batangas City
[11] Sulit, R. C. de la Pena, R. M., and Caguimbal, J. A., 2006,’Efficacy of Chitosan-coated Coconut Charcoal for the Removal of Chromium from Simulated Wastewater’, Batangas State University, Batangas City
[12] A.B. J. Nurul, 2007, ‘The Production and Characterization of Activated Carbon Using Local Agricultural Waste through Chemical Activation Process’: Ph.D. Thesis, Universiti Sains Malaysia, Penang
[13] Jabit, N., 2007,’The Production and Characterization of Activated Carbon Using Local Agricultural Waste Through Chemical Activation Process’, India
[14] Cuhadar, C., 2005, ‘Production and Characterization of Activated Carbon from Hazelnut Shell and Hazelnut Husk’, Middle East Technical University, Malaysia
[15] Jovanovic, V., 2011, ‘Influence of Chemical agents on the Surface Area and Porosity of Active Carbon Hollow Fibers’, Journal of Serbian Chemical Society, Vol 76, No. 9, p. 1283-1294
[16] Ademiluyi, F. T., 2009, Adsorption and Treatment of Organic Contaminants using Activated Carbon from Waste Nigerian Bamboo’, J. Appl. Sci. Environ.Manage.,Vol 13, No. 3, p. 39 - 47