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Photocatalysis Of Basic Black 2 (Janus Black) Dye Using Titanium Dioxide Doped With Zinc (Zn-Tio2)

Volume 1 - Issue 4, October 2017 Edition
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Author(s)
Ayebe B, Yelling M, Amana B.S, Obadahun J, Pascalina P. L
Keywords
Catalyst, Dye, Mineralization, Photo-catalysis, Titanium dioxide.
Abstract
Photo-catalysis of Basic Black 2 (Janus Black) dye was carried out to evaluate the Effect of Time, Metal load Concentration and Light source on the Photo-degradation of Basic Black 2 dye. The catalyst was synthesized by wet-impregnation of Zinc onto Titanium dioxide followed by calcinations at 5000C. The catalyst characterization results indicated that the synthesized TiO2 powder had a pure two phases of Anatase and Rutile structures. The level of mineralization of Basic Black 2 dyes was monitored by taking the absorbance of the dye solution before and after irradiation with the light source at an interval of 20 minutes. The results obtained as shown in Figure 5 and 7 indicated that the efficiency of Photo-degradation of Basic Black 2 dye was 99.92%, 95.94% and 74.46% using 1%, 3% and 5% Zn-TiO2 under Visible light and 98.22%, 97.46% and 73.61% using 1%, 3% and 5% Zn-TiO2 under UV light after irradiation for 80 Minutes respectively.
References
[1] Robert Thornton Morrison, Robert Neilson Boyd, Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd, Seventh Edition, page 1095-1096, 2011.

[2] Manjusha Kulkarni and Pragati Thakar, ‘‘Photocatalytic Degradation and Mineralization of Reactive Azo Dye using semi-conductor metal oxide nanoparticles’’ pp. 245-249, 2014

[3] Kvavadze E, Bar-Yosef O, Belfer-Cohen A,BoarettoE,Jakeli N, Matskevich Z, Meshveliani T, 30,000 year old wild flax fibers, 2009.
\
[4] S.A. Abo-Fara, ‘‘Photocatalytic degradation of Monoazo and Diazo Dyes in wastewater on Nanometer-Sized TiO2’’ Chemistry Department, Faculty of Science, Al-Azhar University (Girls), Naser city, Cairo Egypt, Vol.2(7), 2010.

[5] Lachheb, H., E. Puzenat, "Photocatalytic degradation of various types of dyes (Alizarin S, Crocein Orange G, Methyl Red, Congo Red, Methylene Blue) in water by UV irradiated titania" Applied Catalysis B: Environmental 39(1): pp. 75-90, 2002

[6] N. Laid, N. Bouanimba, R. Zouaghi and T.Sehili, ‘‘Study of the Photocatalytic Degradation of cationic Dye in aqueous solution by different types of catalyst’’ 2014.

[7] Jatinder Kumar, Ajay Bansal, ‘‘Dual Effect of Photocatalysis and Adsorption in Degradation of Azorubine Dye using Nanosized TiO2 and Activated Carbon Immobilized with Different Techniques’’ International Journal of ChemTech Research CODEN (USA) Vol.2, No.3 pp. 1537-1543, 2010

[8] Tehurisa Ohno, Koji Sarukawa, KojiroTokieda, MichioMatsumura,‘‘Morphology of TiO2 Photocatalyst (Degussa, p-25) consisting of Anatase and Rutile crystalline phase’’ Journal of catalysis, Vol. 203, pp. 82-86, 2001.

[9] Chun-Hsing Wu, Hung-Wei Chang, Jia-Ming Chern, ‘‘Basic dye decomposition kinetics in a photocatalytic slurry reactor’’ Journal of hazardous material B137, 2005.

[10] M. Shanthi, V. Kuzhalosai , "Photocatalytic Degradation of an Azo dye, Acid Red 27, in aqueous solution using nano ZnO’’ Indian Journal of Chemistry Vol.5 Pp. 428- 434, 2011.
[11] Wooyul Kim, Takashi Tachikawa, TetsuroMajima and Wonyong Choi, ‘‘Photocatalysisof Dye-Sensitized TiO2 Nanoparticles with Thin Overcoat of Al2O3: Enhance activity for H2 production and Dechlorination of CCL4, 2009.

[12] Ahmed Hassan Ali, ‘‘Study on the photocatalytic degradation of indigo carmine dye by TiO2 photocatalyst’’ Vol. 11 No.2, Journal of Kerbala University, 2013.

[13] Kazuhito Hashimoto, H.I, Akira Fujishima, ‘‘TiO2 Photocatalysis: A Historical Overview and future prospects’’ Japanese Journal of Applied Physics, Vol. 44(12) pp. 8269-8285, 2005

[14] Li Yan-chang, Zou Lin-da, Eric Hu, "Photocatalytic degradation of dye effluent by titanium dioxide pillar pellets in aqueous solution’’ Journal of environmental sciences Vol. 16, No. 3 Pp 375-379, 2004

[15] Jan Sima, Pavel Hasel, ‘‘Photocatalytic Degradation of Textile Dyes in TiO2/UV system’’ The Italian Chemical Engineering Transaction, Vol. 32 pp. 79-84. DOI: 10.3303/CET1332014, 2013

[16] Peternel I.T, Koprivanac N., Locaric Bozic A. M, Kusic H.M, ‘‘Comparative study of a UV/TiO2, UV/ZnO and photo-fenton processes for organic reactive dye degradation in aqueous solution’’ Journal of Hazardous Materials, Vol. 148 Pp. 477-484, 2007.

[17] Kurtoglu M. E., Longenbach T., Gogotsi Y, "Preventing Sodium Poisoning of Photocatalytic TiO2 Films on Glass by Metal Doping" International Journal of Applied Glass Science 2 (2): pp. 108–116, 2011

[18] L.G. Devi, N. Kottam, B. N. Murthy, S.G Kumar, "Enhanced Photocatalytic activity of metal Mn2+, Ni2+ and Zn2+ doped polycrystalline Titania of Analine Blue under UV/Solar light’’ Journal of molecular catalysis, Vol. 328 pp. 44-52, 2010.

[19] Kunal Mondal, Ashutosh Sharma, ‘‘Photocatalytic Oxidation of Pollutant dyes in wastewater by TiO2 and ZnOnano-materials – a mini-review Department of Chemical Engineering, Indian Institute of Echnology,Kkanpur, India’’, 2010

[20] Preeti Mehta, Rajeev Mehta, Menka Suranaa, B. V. Kabrab, ‘‘Influence of Operational Parameters on Degradation of Commercial Textile Azo dye acid blue 113 (Cyanine 5R) by Avanced Oxidation Technology’’ J. Curr. Chem. Pharm. Sc.15, 2011.

[21] P. R. Potti, V. C. Srivastava, "Effect of Dopants on ZnO Mediated Photocatalysis of Dye Bearing Wastewater: A Review", Materials Science Forum, Vol 757, pp.165-174, 2013

[22] R.Chakraborty, D. Roychowdhury, ‘‘Fish bone derived natural hydroxyapatite- supported copper acid catalyst: Taguchi optimization of semibatch oleic esterification’’ Chemical Engineering Journal, 215-216 pp. 491-499, 2013.

[23] N.N Greenwood, A. Earnshaw, Chemistry of Elements, Butterworth- Hainemann Oxford UK, 2nd Edition, 1997.